| Cerium
Cerium,
the second element in the Lanthanide series, is the
most abundantly prevalent rare earth element and is
chemically characterized by having two stable, readily
accessible valence states (III and IV) which make it
perfect for many different uses.
Cerium is an environmentally critical
component in the manufacture of all kinds of environmental
protection and pollution-control systems, from automobiles
to oil refineries. One of the crucial chemical components
in catalytic converters is Cerium oxide (or other Cerium
compounds). Other Cerium-based pollution control catalysts
help to significantly reduce the sulfur oxide emissions
from oil refineries. Cerium is used as a diesel fuel
additive for micro-filtration of pollutants and will
also promote more complete fuel combustion thus reducing
un-combusted smoky particulate and provide for a more
energy efficient engine. Cerium is also used as a recycled
oxidant for performing low temperature, energy efficient
waste treatment on many pollutants.
Cerium oxide slurried in water is the
active ingredient in polishing compounds for glass,
television faceplates, mirrors, optical glass, silicon
microprocessors and disk drives. Cerium is also used
to de-colorize glass for applications such as containers
or tableware. The glass is initially colored by the
metal contaminates present in the raw materials used
to produce glass. Cerium oxide is strong enough to oxidize
these metals to different states thereby eliminating
the unwanted color. TV glass contains cerium to shield
us from harmful UV radiation emitted within the tube.
The fact that the TV screen remains clear after prolonged
use is also due to Cerium. Photographic filters can
contain Cerium for the shielding properties.
Computers contain cerium polished disk
drives and silicon micro-processors as well as cerium
treated glass in the monitor screens. Certain Cerium
compounds are used in thin surface coatings applied
to optical components to improve performance. The compounds
have a refractive index suitable for building up the
multiple layers deposited on lenses, sensors, mirrors,
etc.
Cerium, typically doped with Terbium,
is an essential component in several of the new generation
of phosphors used in tricolor lamps that have made possible
more efficient and more compact fluorescent lighting.
The addition of Cerium oxide to zirconia
produces a high temperature engineering ceramic having
exceptional toughness and good strength. The US Space
Shuttle program is dependent on engineering ceramics
containing Cerium which is also incorporated into other
shuttle components. The oxide has a high refractive
index and is an opacifying agent in enamel compositions
used as protective coatings on metals.
Cerium improves the physical properties
of high-strength, low-alloy steels due to its affinity
to scavenge oxygen and sulfur. Cerium is added primarily
to provide sulfide shape control. Chromium plating quality
is improved with the addition of cerium fluoride to
the electroplating bath. The solubility of the cerous
fluoride is virtually independent of the temperature
of the plating solution thereby stabilizing the active
chromium intermediate necessary for quality plating.
Cerium is also used in the reduction and co-precipitation
removal of waste chromium generated during the plating
process.
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