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Other
Rare Earths
Most of the remaining lanthanides fall into the group
known as the “heavies” and include: Samarium,
Gadolinium, Dysprosium, Terbium, Holmium, Erbium, Thulium,
Ytterbium, and Lutetium.
Samarium offers spectral absorption bands around 950
and 1100 nm that make it useful in filter glasses that
surround Neodymium laser rods to increase operating
efficiency. Alloys containing Samarium are used in high
temperature stable permanent magnets that help make
many devices smaller and more powerful. Samarium cobalt
alloys are used in high-temperature-stable permanent
magnets that are among the most powerful produced and
are used in such items as miniature speakers. Samarium
oxide forms stable complex titanates that have useful
dielectric properties suitable for capacitors, particularly
at microwave frequencies. Samarium is also used in glass
and tile pigmentation.
Gadolinium’s unique magnetic behavior allows
this Lanthanide to be used in alloys that form the heart
of magneto-optic recording technology used for handling
computer data. Many such data storage devices utilize
Gadolinium. Super computers contain Gadolinium based
bubble-memory crystal substrates. Magnetic resonance
imaging (MRI) systems use materials containing Gadolinium
to enhance the resulting images. Gadolinium is also
the single most efficient component used in the detection
of power plant radiation leaks.
Dysprosium is a popular heavy that helps to make electronic
components smaller and faster. Dysprosium oxide is an
additive in special ceramic compositions for producing
high-capacitance, small-size capacitors for electronic
applications. Dysprosium is also an additive for enhancing
coercivity in NdFeB high-strength permanent magnets.
Terbium helps give us energy efficient fluorescent
lamps and Terbium metal alloys help to provide suitable
metallic films for magneto-optic recording of data.
Holmium is one of the least abundant rare earth elements
and has few commercial uses.
Erbium can be found as an amplifier for fiber optic
data transmission (since Erbium fortuitously loses efficiently
at 1.55 microns). Lasers based on Erbium have been introduced
for medical and dental uses because they are suited
to energy delivery without thermal build-up in human
tissue. Erbium is also used in glass coloration where
its stability ensures that glass formulations using
it will be colored pink. It is the only pink colorant
truly stable in glass melts and is used in sunglasses
and decorative crystal glassware.
Thulium, the rarest of the "rare earths",
is a typical heavy lanthanide with chemistry similar
to Yttrium. Its most specific property is, upon appropriate
excitation, an emission in the blue. The luminescence
of Tm, for example, under X-ray excitation is in the
near u.v (˜375 nm) and blue (˜465 nm), closely
matching the sensitivity of normal photographic film.
It can be used in sensitive Xray phosphors to reduce
X-ray exposure.
Ytterbium resembles Yttrium in broad chemical behavior.
The metal when subject to very high stresses increases
its electrical resistance by an order of magnitude and
is used in stress gauges to monitor ground deformations
caused, for example, by nuclear explosions.
Lutetium, the last member of the Lanthanide series
is, along with thulium, the least abundant. It is recovered,
by ion-exchange routines, in small quantities from yttrium-concentrates
and is available as a high-purity oxide. Cerium-doped
lutetium oxyorthosilicate (LSO) is currently used in
detectors in positron emission tomography (PET).
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