Niobium

At A Glance: Nb

Atomic Number: 41
Atomic Symbol: Nb
Atomic Weight: 92.9064
Electron Configuration: [Kr]5s14d4
Atomic Radius: 207 pm (Van der Waals)
Melting Point: 2477 °C
Boiling Point: 4744 °C
Oxidation States: 5, 3
Sources: The element is found in niobite (or columbite), niobite-tantalite, parochlore, and euxenite. Large deposits of niobium have been found associated with carbonatites (carbon-silicate rocks), as a constituent of parochlore. Extensive ore reserves are found in Canada, Brazil, Nigeria, Zaire, and in Russia.

Uses: Niobium is a shiny, white, soft, and ductile metal, and takes on a bluish cast when exposed to air at room temperatures for a long time. The metal starts to oxidize in air at 200°C, and when processed at even moderate temperatures must be placed in a protective atmosphere.

Content provided by Los Alamos National Laboratory. Used with permission.

Rare earth element - Niobium
Rare earth element - Niobium
Niobium Spin Video

Photos of rare earth elements used on our site are copyright of Max Whitby and Theodore Gray. Used with permission.

Niobium is a rare metal that is integral to a wide range of applications.  One of the most exciting is in superconducting materials.  Superconductive magnets have been made with Nb-Zr wire, which retains its superconductivity in strong magnetic fields. This type of application offers hope of direct large-scale generation of electric power — and with all of the tremendous energy efficiency benefits that superconductivity promises.

History

(Niobe, daughter of Tantalus) Discovered in 1801 by Hatchett in an ore sent to England more than a century before by John Winthrop the Younger, first governor of Connecticut. The metal was first prepared in 1864 by Blomstrand, who reduced the chloride by heating it in a hydrogen atmosphere. The name niobium was adopted by the International Union of Pur and Applied Chemicstry in 1950 after 100 years of controversy. Many leading chemical societies and government organizations refer to it by this name. Most metallurgists, leading metal societies, and all but one of the leading U.S. commercial producers, however, still refer to the metal as “columbium.”

Sources

The element is found in niobite (or columbite), niobite-tantalite, parochlore, and euxenite. Large deposits of niobium have been found associated with carbonatites (carbon-silicate rocks), as a constituent of parochlore. Extensive ore reserves are found in Canada, Brazil, Nigeria, Zaire, and in Russia.

Properties

It is a shiny, white, soft, and ductile metal, and takes on a bluish cast when exposed to air at room temperatures for a long time. The metal starts to oxidize in air at 200°C, and when processed at even moderate temperatures must be placed in a protective atmosphere.

Isotopes

Eighteen isotopes of niobium are known. The metal can be isolated from tantalum, and prepared in several ways.

Uses

It is used in arc-welding rods for stabilized grades of stainless steel. Thousands of pounds of niobium have been used in advanced air frame systems such as were used in the Gemini space program. The element has superconductive properties; superconductive magnets have been made with Nb-Zr wire, which retains its superconductivity in strong magnetic fields. This type of application offers hope of direct large-scale generation of electric power.

Source: Los Alamos National Laboratory; Molycorp

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